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Can you provide any evidence to support your hypothesis?
In a graph of earth IR emission spectra, we see the dip at 15 um,
if much of the CO2 re-emitted at the same 15 um, the dip would not be deep.
For CO2, excitation is like a spinning top.
it does not have a smooth path to ground state, and the last stage emissions are a collection of far IR and RF.
Think about the spinning top, when it finally comes to rest, which way is it pointing?
the answer is random, because, each spin produces a slightly different set of conditions.
Did the top smoothly come to a stop, or did it bounce several times.
https://scienceofdoom.files.wordpre...e_near_the_ground-geiger-2003-499px.png?w=500
Notice what happens to the emission spectra of CO2 after 10 um, it is almost full,
these are the many small steps of the top bouncing randomly to a halt.