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There is. Actually, I looked someplace I didn't before. I had it saved. By my save file date, it was probably 5 years ago we discussed it here. I get pretty board rehashing things that people forget. Had to open several files before finding it though. You can find the study by the title:
View attachment 67332422
There are others, but I had this one handy
While this is a review of a different "paper" by Hermann Harde ("Scrutinizing the carbon cycle and CO2 residence time in the atmosphere". 2017), it shows his basic lack of understanding as to what is going on in the atmosphere as regards human produced CO2:
"Dr. Harde makes three fundamental errors: Using the residence time, or even the decay rate of the 14C bomb tests excess, doesn't say anything about the time needed to reduce an extra bulk CO2 injection - whatever the source - above the temperature controlled steady state of the oceans with the atmosphere. Using the total concentration of CO2 in the atmosphere as base implies a steady state of zero CO2 in the atmosphere, which is not realistic. Using only natural emissions without taking into account the natural sinks violates the mass balance.
Besides that, the "temperature fits almost all" solution violates about every single observation in the atmosphere, oceans and vegetation, while the human cause fits them all. Like the mass balance, the decline of δ 13C level (in atmosphere, ocean surface and vegetation), the pre-1950 change in 14C, the changes of pH and DIC in the ocean surface, the change in oxygen balance and last but not least Henry's law for the solubility of CO2 in seawater [11]."
And more:
"I don’t need to say too much about the details of our paper. It essentially highlights that the Harde paper confuses the residence time of an individual molecule (years) with the adjustment time for an enhancement of atmospheric CO2 (centuries). It also points out that you can’t model the evolution of atmospheric CO2 with a single equation. You need to consider at least two reservoirs (atmosphere and surface ocean) and this requires at least two equations that are solved simultaneously.
We also point out that it’s important to consider the Revelle factor, which limits how much of our emissions can be taken up by the oceans (we would expect – depending on how much we emit – that 20-30% of our emissions will remain in the atmosphere for thousands of years). Additionally, there were issues with Harde’s application of his model to paleoclimate, and there were a number of papers that he really should have cited (such as citing Essenhigh 2009 paper, while failing to cite Gavin Cawley’s response)."
A Harde response
Earlier this year, I wrote a post about a paper by Hermann Harde that argued that most of the rise in atmospheric CO2 was natural. If you want more details of why this suggestion is nonsense, you c…
andthentheresphysics.wordpress.com
Here is a link to Harde's paper that is questioned above: https://www.sciencedirect.com/science/article/abs/pii/S0921818116304787